Hydrogen Peroxide – The Good, the Bad, and the Ugly!
Hydrogen Peroxide (H2O2) is essentially water that’s taken advantage of a ‘two for one’ deal on oxygen atoms. This extra oxygen atom turns out to be a right busybody and lends this substance some very interesting properties…..
The Good…
A clean, oxygenated nutrient solution is liquid heaven for your plants. A pathogen-free nutrient solution allows your plants to get on with the process of growing and blooming without the energy-sapping distractions of fighting off nasties. And, of course, oxygen in your nutrient solution is just the ticket for healthy, vigorous root development. That’s why so many growers swear by hydrogen peroxide – it both cleans and oxygenates! “Cash back!”, as my friend Mr Partridge would say…
Hydrogen peroxide decomposes when it’s added to water. That is, hydrogen peroxide (H2O2) becomes water (H2O). However something has to happen to the extra oxygen atom, or oxygen radical as it is sometimes called – just a posh, chemical term for a solitary, unpaired electron. Radicals (also known as ‘free radicals’) are usually highly reactive, so they are highly likely to take part in chemical reactions. So essentially, a small amount of hydrogen peroxide added to your nutrient solution introduces countless ‘roaming radicals’ looking for a bit of action. Not unlike your local high street on a Friday night ten minutes after closing time …
Any lingering pathogens in your nutrient solution are neutralised as the oxygen radical attaches itself to the pathogen cells – this process is known as oxidisation. This renders the pathogens harmless as, now that they have their ‘hands full’ with the extra oxygen atom, they no longer have the capacity to get a hold on your plants. Essentially, your nutrient solution is ‘disinfected’.
This isn’t the end of the story, however. Oxygen is soluble in water. So, any remaining oxygen can be absorbed into the nutrient solution. The solubility of oxygen is dependent on temperature – the optimum is around 18 degrees Celsius.
One commercially available form of hydrogen peroxide is Oxy-Plus (also known as Liquid Oxygen) – it contains 17.5% H2O2. (Incidentally, Growth Technology, the manufacturers of Oxy-Plus, also make Oxy-Plus test strips which allow you to easily measure the level of oxygenation in your nutrient solution.)
You may hear of some growers who claim that H2O2 aids seed germination. In actual fact all it does is help to create a sterile environment. To 500ml of lukewarm water add 10 drops Oxy-Plus and mix well. Then soak the seeds in this solution for about 24 hours. Some growers sterilise their rockwool cubes using a similar (pH adjusted) solution and adding an early-stages dilute fertiliser such as Formulex) – but these mediums are pretty sterile in the first place. Personally I think all this is complete overkill and simply introduces other factors that could go wrong (like getting the concentration wrong, etc).
As for Hydroponics systems, most growers add 5ml Oxy-Plus, or a similar product, to every ten litres of nutrient solution. Make sure you stir thoroughly before allowing it to come into contact with your plants. Try diluting the amount of H2O2 product you require in a litre or two of lukewarm water first and then add this to the tank.
This procedure should be carried out two to three times a week to maintain optimum concentration in the tank. If you have the time to add Oxy-Plus every day then try adding it at the rate of 5ml per 20 litres of nutrient solution.
Hydrogen peroxide can be used to clean and sterilise your system and growing medium after your harvest. Once it has finished disinfecting it will reduce to harmless substances and will therefore pose no risk to future crops.
You can also use a hydrogen peroxide solution (5 mls Oxy-Plus to every litre of water) to circulate around your system in order to sterilise all your drippers and pipes etc. Just be sure to flush everything through afterwards with pure water before starting your next crop.
Wow – all this from the same bottle? I’m starting to sound like I’m on some sort of commission. So but before I get too carried away extolling its praises we need to explore the other side of the coin …
The Bad…
Right, so we’ve established that hydrogen peroxide is a strong oxidiser. It breaks down into water and the free oxygen radical is left to roam looking for trouble to sort out. Well, sorry folks, it isn’t all good news. In fact, aside from my overuse of real-world analogies to tenuously describe chemical reactions, I wouldn’t be surprised if that last section was making some growers’ blood boil!
So what’s the problem? Well, let’s come back to this oxidisation property. Some growers outlaw the use of hydrogen peroxide precisely because it’s such a potent oxidiser. If your nutrient solution doesn’t contain any pathogenic organisms then this free oxygen radical is sort of ‘unemployed’ – and we all know that the devil makes work for idle thumbs, eh? As well as causing oxidative stress damage to your plants’ roots causing chlorosis, necrosis, and stunting, hydrogen peroxide added to a healthy system can oxidise the very nutrients that your plants need to feed on! Essentially hydrogen peroxide can change the ionic form and ionic radius of nutrients which can adversely affect nutrient uptake by your plants’ roots. However, this isn’t a problem in an unclean, diseased system as the free oxygen radical will attack pathogens first – and leave your nutrients well alone.
You can use an airpump to bubble air into your nutrient solution to increase its oxygenation. You can also use products such as Guardian Angel and Trichoderma powder as a preventative measure against pythium.
That said, the optimum temperature for absorption of nutrients ranges between 23 to 26 degrees Celsius – significantly higher than the optimum temperature for oxygen absorption.
Remember –if you are using enzyme products such as ‘cannazym’ or ‘sensizym’ you should avoid introducing any H2O2 products into your nutrient solution. The only enzyme product that we are aware of that’s OK to use with a low ppm of hydrogen peroxide is ‘Hygrozyme’. If in doubt, ask at your local grow shop.
The Ugly…
Hydrogen peroxide, either in pure or diluted form, can pose several risks:
Above roughly 70% concentrations, hydrogen peroxide can give off a vapour that can detonate above 70 °C (158 °F) at normal atmospheric pressure. This can then cause a boiling liquid expanding vapour explosion of the remaining liquid – a verbose way of saying that all hell breaks loose.
Only a crazy fool, or a highly trained scientist, would ever try to distil hydrogen peroxide – even at normal pressures it’s highly dangerous.
Hydrogen peroxide vapours can form sensitive contact explosives with hydrocarbons such as greases. Hazardous reactions ranging from ignition to explosion have been reported with alcohols, ketones, carboxylic acids (particularly acetic acid), amines and phosphorus. Many a chemist’s death has been linked to a ‘peroxide’ of some form or other. But perhaps the darkest side to hydrogen peroxide was heard by the jury in the 21st of July terror trial where it was alleged that the accused men bought hydrogen peroxide and mixed it with chapatti flower to make explosives.
Hydrogen peroxide, if spilled on clothing (or other flammable materials), will preferentially evaporate water until the concentration reaches sufficient strength, then clothing will spontaneously ignite. Leather generally contains metal ions from the tanning process and will often catch fire almost immediately.
Concentrated hydrogen peroxide (>50%) is corrosive, and even domestic-strength solutions can cause irritation to the eyes, mucous membranes and skin. Swallowing hydrogen peroxide solutions is particularly dangerous, as decomposition in the stomach releases large quantities of gas (10 times the volume of a 3% solution) leading to internal bleeding. Inhaling over 10% can cause severe pulmonary irritation.
Finally, and perhaps most disturbingly, hydrogen peroxide has been linked to some of the biggest mistakes in the world of hairdressing.
Alternative Sterilising Products
Pythoff
- An advanced full spectrum sterilising agent that eliminates pathogens from all parts of your hydroponic system. It has a unique formulation that dissolves directly into your nutrient solution and remains active as a sterilising agent for longer. Perfect for both the prevention and treatment of pythium infections but remember not to use in conjunction with beneficial bacteria or fungi based products.
Microbial
- Microbial conditions the root zone of your plants – it’s powerful stuff, however, and will wipe out all bacteria, fungi, algae and viruses – infact all biological contaminants, good or bad! That said, it’s a very effective treatment against root pathogens such as pythium.
Alternative Oxygenation
Air pumps
- Higher levels of oxygen in the root zone increases the rate of nutrient uptake – this equals faster growing plants and that, in turn, can lead to an increased yield. Air pumps oxygenate your nutrient solution by continuously bubble air into it. You can pick them up for around fifty quid and they work almost silently with low power consumption. Just be sure to check if your particular pump is submersible or not! (The non-submersible variety work by pumping air into your nutrient solution via a tube.)
Thanks to UrbanGardenMagazine for the interesting article! Original link here
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